Engineering nickel catalysts with atomic-sulfur-stabilized thiolate adlayers for durable selectivity in hydrogenation of halonitrobenzenes

Fuente: Green Chemistry
Green Chem., 2026, 28,5780-5787DOI: 10.1039/D5GC06883E, PaperYujian Fan, Xuechun Sang, Juwen Gu, Qian Zhang, Songbai Qiu, Tiejun WangDurable Ni catalyst with atomic-sulfur critically stabilized thiolate adlayers achieves >99.9% selectivity in halonitrobenzene hydrogenation via upright adsorption, suppressing dehalogenation for minimal waste and high atom economy.The content of this RSS Feed (c) The Royal Society of Chemistry