Fecha de publicación: -- Fuente: Journal of applied polymer Lugar: RESEARCH ARTICLE Incorporating wollastonite, zirconium phosphate, and mica into ethylene-vinyl acetate yields advanced ceramifiable composites that delay ignition by 325%. During combustion, a dense char layer forms, suppressing peak heat release by 75.8% and smoke production by 31.1%. At 1000°C, the structure transforms into a robust anorthite-apatite-ZrO2 ceramic skeleton, delivering superior structural stability.

ABSTRACT
Ceramizable polymers offer exceptional structural stability and fire safety for high-temperature applications. This study presents a highly flame-retardant ethylene-vinyl acetate copolymer (EVA) composite, engineered through the synergistic incorporation of wollastonite fiber (WF), layered zirconium phosphate (ZrP), and a glass powder/mica filler. While the control composite exhibited severe melt spreading, the synergistic system maintained robust structural integrity at 1000°C. X-ray diffraction (XRD) revealed that WF and ZrP altered the ceramization behavior, generating stable crystalline phases, including anorthite, an apatite-type calcium phosphate phase, and monoclinic ZrO2. During 50 kW/m2 combustion tests, the optimized composite demonstrated outstanding fire retardancy and smoke suppression. Compared to the control, it prolonged the time to ignition (TTI) by 325% and reduced the peak heat release rate (PHRR) by 75.8%, total heat release (THR) by 39.8%, peak smoke production rate (PSPR) by 67.5%, and total smoke production (TSP) by 31.1%. Mechanistically, WF and ZrP promote early matrix cross-linking and ceramification, accelerating the formation of a multiphase ceramic structure. This yields a stable inorganic network reinforced by KZr2(PO4)3, which acts as a dense thermal and mass barrier in the condensed phase. Ultimately, this work provides valuable insights for designing advanced, high-temperature-resistant polymers.