Fuente: Polymers Polymers, Vol. 18, Pages 777: Improving and Optimizing Mechanical Properties of Glass Fiber-Reinforced Composites via Geometric Optimization of Nanofillers Using Co-Curing Processes
Polymers doi: 10.3390/polym18060777
Authors:
Eonsu Yun
Hyunjong Choi
Joon Seok Lee
Byoung-Sun Lee
Hyunchul Ahn

This study investigates the effects of the co-curing process and nanoparticle reinforcement on the mechanical performance of plain-woven glass fiber-reinforced plastic (GFRP) adhesive joints, aiming to address the limitations of traditional fastening methods and the inherent brittleness of epoxy adhesives. Specifically, spherical silica (SiO2) and plate-like graphene nanoplatelets (GNPs) were incorporated into the epoxy matrix at varying concentrations (0.25 to 1.0 wt.%) to evaluate the influence of particle geometry on joint integrity. Experimental results demonstrated that the co-curing technique yields superior mechanical properties compared to secondary bonding, exhibiting improvements of 35% in shear strength (from 10.97 MPa to 14.83 MPa) and 12% in flexural strength (from 72.57 MPa to 81.28 MPa) due to enhanced chemical interlocking. Furthermore, the addition of nanoparticles significantly improved joint performance, with the optimal content identified at 0.75 wt.% for both particle types. Notably, GNPs outperformed SiO2, enhancing shear and flexural strengths compared to the neat co-cured baseline. Ultimately, the 0.75 wt.% GNP-reinforced material exhibited a shear strength of 21.22 MPa and a flexural strength of 104.09 MPa. Morphological analysis revealed that while SiO2 contributes to reinforcement primarily via crack deflection, the high-aspect-ratio GNPs provide superior energy dissipation through crack bridging and pull-out mechanisms. Consequently, this study suggests that the co-curing process combined with an optimal concentration of GNPs presents a highly effective strategy for maximizing the reliability and structural efficiency of composite joints in weight-critical applications.