Fuente: Polymers Polymers, Vol. 18, Pages 750: Optimization of Bleaching Process and Evaluation of Pulp Performance for Super-Arundo Donax Kraft Pulp
Polymers doi: 10.3390/polym18060750
Authors:
Zhangming Cai
Xingxiang Ji
Jie Liang
Zhongjian Tian
Jingpeng Zhou

With the increasing emphasis and protection on forest resources worldwide, the development of non-wood plant fiber raw materials has become a key path to promote the green and sustainable development of China’s pulp and paper industry. In this study, Super-Arundo donax, a new non-wood fiber raw material, was systematically investigated for its applicability in the bleaching process. Firstly, by adjusting key bleaching technical variables such as alkali dosage, time, oxygen pressure and temperature, the oxygen delignification process of the Super-Arundo donax kraft pulp was optimized. The data revealed that under the experimental conditions of 3.0% alkali dosage, 60 min bleaching time, 100 °C bleaching temperature, 0.6 MPa oxygen pressure and 0.6% MgSO4 dosage, the bleached pulp yield reached 91.58%, the brightness was 42.04% ISO, and its tensile index was 60.92 N·m/g, bursting index was 4.16 kPa·m2/g, and tear index was 5.45 mN·m2/g, respectively. To further enhance the bleaching effect, the study introduced the H2O2 enhanced oxygen delignification process. The alkali dosage, bleaching temperature and H2O2 dosage were selected as the process parameters, with the pulp yield and brightness as the response indicators. A central composite design was adopted to construct a response surface model, and the interaction effects among various factors were analyzed. The optimized optimal process conditions are as follows: pulp concentration 10%, alkali dosage 2.84%, bleaching temperature 105 °C, H2O2 dosage 4.85%, bleaching time 60 min, MgSO4 dosage 0.6%. Under these conditions, the pulp yield was 89.76% and the brightness reached 53.85% ISO. Therefore, Super-Arundo donax possesses excellent pulp-making and papermaking properties, and is expected to serve as a high-quality non-wood fiber raw material to alleviate the pressure on traditional papermaking raw materials and contribute to the green, sustainable and low-carbon transformation of the pulp and paper industry.