Polymers, Vol. 18, Pages 381: Mechanical Properties of Granite Residual Soil Reinforced by Permeable Water-Reactive Polyurethane

Fuente: Polymers
Polymers, Vol. 18, Pages 381: Mechanical Properties of Granite Residual Soil Reinforced by Permeable Water-Reactive Polyurethane
Polymers doi: 10.3390/polym18030381
Authors:
Shuzhong Tan
Jinyong Li
Dingfeng Cao
Tao Xiao
Jiajia Zheng

Granite residual soil (GRS) is highly susceptible to water-induced softening, posing significant risks of slope instability and collapse. Conventional impermeable grouting often exacerbates these hazards by blocking groundwater drainage. This study investigates the efficacy of a permeable water-reactive polyurethane (PWPU) in stabilizing GRS, aiming to resolve the conflict between mechanical reinforcement and hydraulic conductivity. Uniaxial compression tests were conducted on specimens with varying initial water contents (5%, 10%, and 15%) and PWPU contents (5%, 10%, and 15%). To reveal the multi-scale failure mechanism, synchronous acoustic emission (AE) monitoring and digital image correlation (DIC) were employed, complemented by scanning electron microscopy (SEM) for microstructural characterization. Results indicate that PWPU treatment significantly enhances soil ductility, shifting the failure mode from brittle fracturing to strain-hardening, particularly at higher moisture levels where failure strains exceeded 30%. This enhancement is attributed to the formation of a flexible polymer network that acts as a micro-reinforcement system to restrict particle sliding and dissipate strain energy. An optimal PWPU content of 10% yielded a maximum compressive strength of 4.5 MPa, while failure strain increased linearly with polymer dosage. SEM analysis confirmed the formation of a porous, reticulated polymer network that effectively bonds soil particles while preserving permeability. The synchronous monitoring quantitatively bridged the gap between internal micro-crack evolution and macroscopic strain localization, with AE analysis revealing that tensile cracking accounted for 79.17% to 96.35% of the total failure events.