Fuente: Polymers Polymers, Vol. 18, Pages 1366: From Intrinsic Resin Properties to Interlaminar Fracture Toughness of CFRP: Crack-Tip Deformation, Transfer Mechanisms, and Loading-Mode Dependence
Polymers doi: 10.3390/polym18111366
Authors:
Xiuxiang Li
Yunfu Ou
Juan Li
Yiting Weng
Yunxiao Zhang
Anran Fu
Xia Liu
Qizhong Huang
Dongsheng Mao

Interlaminar fracture toughness (ILFT) is a key factor governing the damage tolerance and service reliability of carbon fiber-reinforced polymer (CFRP) laminates. This study aims to clarify how the deformation capability of epoxy resin affects the Mode I and Mode II ILFT of carbon fiber/epoxy laminates under comparable fiber, resin-content, and laminate-configuration conditions. Two epoxy systems were compared: a high-strength/high-modulus (HSHM) resin system, designated as Group B, and a high-toughness (HT) resin system, designated as Group T. Neat resin castings were characterized by tensile and flexural tests, and the corresponding CFRP laminates were evaluated using double cantilever beam (DCB) and end-notched flexure (ENF) tests. Although Group T showed slightly lower tensile strength and modulus than Group B, its elongation at break increased from 4.0% to 6.5%, corresponding to an increase of approximately 62.5%. The Mode I ILFT (GIC) increased from approximately 279 J/m2 for Group B to 487 J/m2 for Group T, while the Mode II ILFT (GIIC) increased from approximately 530 J/m2 to 708 J/m2, corresponding to improvements of approximately 74.6% and 33.6%, respectively. Scanning electron microscopy (SEM) observations indicated that Group T promoted more resin-covered fibers, resin tearing, crack-tip blunting, crack deflection, shear deformation features, and crack-path reconstruction. These results indicate that, within the present two-system comparison, resin ductility-related deformation capability and local crack-tip deformability should be considered together with strength and modulus when evaluating interlaminar crack resistance. The toughening effect also showed loading-mode dependence, with Mode I improvement mainly related to crack-tip blunting and resin tearing, whereas Mode II improvement was mainly associated with matrix shear deformation, resistance to interfacial sliding, and crack-path deflection.