Fuente: Polymers Polymers, Vol. 17, Pages 3186: Chitin-Based Porous Carbon Containing Cuprous Sulfide for Supercapacitor Electrode Materials
Polymers doi: 10.3390/polym17233186
Authors:
Jiangyang Han
Wenchao Yu
Fukun Niu
Yang Hu
Hongmei Qin
Zhuqun Shi
Chuanxi Xiong
Quanling Yang

Chitin-derived biomass carbon materials are promising supercapacitor electrode materials due to their wide availability, low cost, high specific surface area, and nitrogen doping capability. However, their practical application is limited by insufficient conductivity and cyclic stability, often requiring functional modification or integration with complementary materials. In this study, we present a novel strategy by incorporating copper sulfide (Cu2S) into a chitin-based carbon matrix. Cu2S, known for its high intrinsic conductivity, excellent electroactivity, and theoretical specific capacity (~335 mAh·g−1), was uniformly doped into the three-dimensional carbon aerogel framework derived from chitin nanofibers (ChNF) through sol–gel, freeze-drying, and high-temperature carbonization processes. The resulting chitin-based carbon/Cu2S composite aerogel (CChNF/Cu2S) exhibited a hierarchical porous structure with Cu2S nanoparticles (20–30 nm) uniformly distributed on the carbon fiber surface. Electrochemical tests demonstrated its excellent performance, achieving a specific capacitance of 852 F·g−1 at 1 A·g−1, highlighting the synergistic effects of the conductive Cu2S and nitrogen-doped carbon framework for high-performance supercapacitor applications.