Fuente: Textiles (MDPI) Textiles, Vol. 5, Pages 52: Nano-Silica-Modified Hydrophobic PDMS Encapsulation on CNT Thermoelectric Fibers for Waterproof Thermoelectric Textiles
Textiles doi: 10.3390/textiles5040052
Authors:
Boxuan Zhang
Mingyuan Ma
Shengyu Wang
Hanyu Cai
Dawei Li
Peng Gu

Flexible and wearable thermoelectric devices can convert body waste heat into electricity, showing a new direction to solve the long-lasting issue of energy supply on portable devices. However, thermoelectric fibers are prone to short circuits and failure due to sweat stains and washing practices. Therefore, it is quite necessary to solve this problem to realize the practical thermoelectric device. PDMS, with its excellent insulation and flexibility, can effectively address short-circuit issues by encapsulating the surface of thermoelectric fibers. In this work, hydrophilic nano-silica (H-SiO2)-modified PDMS that insulates materials was prepared and coated on the surfaces of polyethyleneimine (PEI)- and hydrochloric acid (HCl)-treated dual-surface-modified thermoelectric fibers. The encapsulated fibers were then woven into spacer fabric to prepare thermoelectric textiles (TETs). After 50 water washing cycles, the fibers retained 97% of their conductivity, and the textiles continued to function normally underwater, indicating that the thermoelectric fibers are effectively protected under PDMS encapsulation.