Fuente: Sustainability - Revista científica (MDPI) Sustainability, Vol. 18, Pages 2655: Evaluation of Waste-Plastic Pyrolysis Oil as a Potential Feedstock for Lubricant Base Oil Production via Hydroprocessing
Sustainability doi: 10.3390/su18052655
Authors:
Jung Hee Jang
Hyun Ji Kim
Jin Ho Kim
Ji Eun Lee
Hyun Sung Jang
Suk Hwan Kang

The environmental concerns associated with the excessive use and improper disposal of plastic waste have led to increased interest in chemical recycling methods such as pyrolysis. In this study, waste plastic pyrolysis oil (WPPO) was evaluated as a potential feedstock to produce high-quality feedstock for lubricant base oils through hydroprocessing. WPPO was obtained via the thermal degradation of waste plastic at 400 °C under a nitrogen atmosphere using a 2 t/day pyrolysis reactor. The physicochemical properties of WPPO were analyzed, including the sulfur, chlorine, and metal contents. A series of Pt-supported catalysts based on different acidic supports (SAPO-11, SAPO-34, and Zeolite Y100) was prepared using an incipient wetness impregnation method and characterized by BET, XRD, and TPD techniques. The hydroprocessing reactions were conducted under varying temperature and pressure conditions to evaluate conversion and optimize product selectivity. The catalysts exhibited different surface areas, pore structures, and acidity profiles, which directly impacted their hydroprocessing performance. The results demonstrate that Pt/Y-100 exhibited the best upgrading performance among the tested catalysts, achieving an olefin-to-paraffin conversion of over 88.65% with a dominant paraffinic hydrocarbon distribution in the C15–C25 range under optimal conditions (300 °C and 40 bar). The results demonstrate that the conversion of olefins to paraffins in WPPO can be effectively controlled by tuning the reaction conditions and catalyst.