Fuente: Polymers Polymers, Vol. 17, Pages 3144: From Waste to Wires: PBAT/Lignin Biocomposites Functionalized by a CO2 Laser for Transient Electronics
Polymers doi: 10.3390/polym17233144
Authors:
Antonella Moramarco
Elio Sarotto
Itziar Otaegi
Nora Aranburu
Federico Cesano
Valentina Brunella
Marco Zanetti
Pierangiola Bracco

Polybutylene adipate terephthalate (PBAT), a flexible biodegradable polyester, has gained widespread use in packaging applications due to its ability to degrade under controlled conditions, producing non-toxic substances. While this property makes PBAT particularly attractive for the development of transient electronic devices, this potential application remains unexplored. To address this research gap, we developed PBAT-based composites and modified their electrical properties through CO2 laser functionalization. Although laser treatment of neat PBAT primarily resulted in material ablation, the incorporation of lignin and silica-based fillers enabled the formation of electrically conductive pathways. Among the various fillers tested, dealkaline lignin (DEALK) and glass fibers (GFs) provided the optimal combination of electrical conductivity, mechanical properties, and processability. Characterization techniques (electrical measurements, optical microscopy, SEM, EDX, and TGA) highlighted that by optimizing laser treatment and the filler concentration, it is possible to produce conductive tracks with remarkably low sheet resistance. Hybrid composites containing 10–15 wt% of GF and 20–25 wt% of lignin demonstrated the best electrical performance with values as low as 3.5 Ω/sq, which were further reduced to 1.72 Ω/sq after laser process optimization. These findings establish PBAT composites as promising candidates for sustainable transient electronics.