Fuente: Polymers Polymers, Vol. 18, Pages 808: CsPbBr3 Perovskite Nanocrystals in P3HT:PCBM Hybrid Photodetectors: Spectral Enhancement and Evidence for Photoinduced Energy Transfer
Polymers doi: 10.3390/polym18070808
Authors:
Fernando Rodríguez-Mas
José Luis Alonso Serrano
Pablo Corral González
Abraham Ruiz Gómez
Juan Carlos Ferrer Millán

We report the enhancement of organic photodetector (OPD) performance through the incorporation of CsPbBr3 perovskite nanocrystals (PNCs) into P3HT:PCBM devices. The optimized device (HPD_01) exhibits a maximum responsivity of 0.083 A/W and a specific detectivity of ~4.7 × 1010 Jones, and a minimum NEP of 5.2 × 10−12 W·Hz−1/2 at the self-powered operating point (V ≈ 0 V), outperforming the nanoparticle-free reference. Frequency- and distance-dependent measurements under visible light communication conditions demonstrate that the optimized device maintains strong signal detection up to 1 MHz and at distances exceeding 15 cm. Notably, the external quantum efficiency spectra reveal an additional contribution in the 450–575 nm range, which is absent in the reference device. This enhancement is consistent with a radiative absorption–reemission energy-transfer mechanism, supported by quantitative spectral overlap analysis showing that 99.5% of the PNC photoluminescence falls within the 450–575 nm EQE enhancement window and that the maximum differential EQE gain occurs at 519 nm—only 2 nm from the PNC emission peak. Our results suggest that controlled PNC incorporation enables efficient optical energy coupling, leading to high-sensitivity, fast-response OPDs suitable for optical communication applications.