Fuente: Sustainability - Revista científica (MDPI) Sustainability, Vol. 18, Pages 4759: Closing Material and Water Loops in Lithium-Ion Battery Recycling: Integrated Nanofiltration–Membrane Distillation for Sustainable Metal Recovery
Sustainability doi: 10.3390/su18104759
Authors:
Thiago Vinícius Barros
Franciele Pereira Camacho
Leandro Vitor Pavão
José Augusto de Oliveira
Ana Caroline Raimundini Aranha
Abhijit Data
Biplob Pramanik
Linhua Fan
Veeriah Jegatheesan
Lucio Cardozo-Filho

This study investigates the integration of nanofiltration (NF) and membrane distillation (MD) for the selective separation and recovery of critical metals from effluents generated by supercritical water oxidation (SCWO) of lithium-ion batteries. Beyond resource recovery, the proposed hybrid system addresses the urgent environmental challenge associated with highly contaminated battery recycling effluents, which pose severe risks to aquatic ecosystems if improperly managed. NF90 and NF270 membranes exhibited complementary behavior: NF90 achieved high rejection of Co, Ni, and Mn (>70%) with a minimum lithium rejection of 30%, whereas NF270 showed lower rejection of divalent metals (40%) and lower lithium rejection (<20% at pH = 7), along with a higher permeability. Subsequent MD enabled water recovery while concentrating lithium in the MD concentrate (brine), maintaining near-complete rejection of transition metals (>90%) and reducing the effluent conductivity by more than 85%. Surface characterization (SEM–EDS, AFM, BET, and contact angle) revealed fouling mechanisms and wettability loss, highlighting operational stability limitations. In this hybrid approach, nanofiltration enables the selective separation of lithium from transition metals, while membrane distillation promotes water recovery and concentrates lithium into a recoverable brine, with fouling and wetting defining the operational boundaries of the process. Overall, the results demonstrate that coupling SCWO with NF–MD represents a viable and scalable pathway for simultaneous effluent detoxification and lithium recovery, contributing to circular economy strategies and the sustainable management of battery-recycling wastewater.