Fecha de publicación: 19/11/2024 Fuente: Molecules - Revista científica (MDPI) Molecules, Vol. 29, Pages 5452: PLA- and PHA-Biopolyester-Based Electrospun Materials: Development, Legislation, and Food Packaging Applications
Molecules doi: 10.3390/molecules29225452
Authors:
Cristian Patiño Vidal
Cristina Muñoz-Shugulí
Manon Guivier
Débora Puglia
Francesca Luzi
Adrián Rojas
Eliezer Velásquez
María José Galotto
Carol López-de-Dicastillo

The high accumulation of plastic waste in the environment has led to great interest in biodegradable polymers, such as polylactic acid (PLA) or polyhydroxyalkanoates (PHAs). Their benefits, combined with the application of electrospinning technology, represent an innovative proposal for the food packaging industry. This article provides a comprehensive review of the latest developments of PLA- and PHA-biopolyester-based electrospun materials for food packaging applications, summarizing the reported technologies, material properties, applications, and invention patents. In addition, the legislation used to assess their biodegradability is also detailed. Electrospun packaging materials are largely developed through uniaxial, coaxial, emulsion, multiaxial, and needleless techniques. PLA- and PHA-biopolyester-based electrospun materials can be obtained as single and multilayer packaging structures, and the incorporation of natural extracts, organic compounds, and nanoparticles has become a great strategy for designing active food packaging systems. The biodegradability of electrospun materials has mainly been evaluated in soil, compost, and aquatic systems through ASTM and ISO normatives. In this review, the dependence of the biodegradation process on the polymer type, conditions, and test methods is clearly reviewed. Moreover, these biodegradable electrospun materials have shown excellent antioxidant and antimicrobial properties, resulting in a great method for extending the shelf life of fruits, bread, fish, and meat products.