Fecha de publicación: 14/11/2024 Fuente: Journal of applied polymer Lugar: RESEARCH ARTICLE Surfacing coating of multi-walled carbon nanotube (MWCNT) with polyphenols (PNs) can improve the dispersion of MWCNT within silicone matrix, which therefore ensures low modulus and high electric breakdown strength of the MWCNT@PNs/silicone rubber (SR) multilayered composites. Meanwhile, multilayered structure modulation further prohibits the premature electrical breakdown. Consequently, the multilayered composites show excellent electromechanical deformability with good stability.


Abstract
Silicone rubber (SR) is an ideal dielectric elastomer substrate due to its excellent flexibility and fast response speed. However, the innate low dielectric permittivity (ε) of SR generally requires a rather high driving voltage that restricts its widespread application. Typical attempts to increase ε of SR usually deteriorate either its flexibility or electrical stability. Herein, conductive multi-walled carbon nanotube (MWCNT) were first surface modified with polyphenols (PNs) (MWCNT@PNs), aiming to facilitate its well dispersion within SR matrix, which may maintain the softness and electrical stability of SR via suppressing concentrated physical crosslinking and local leakage current flow. Then, five-layered MWCNT@PNs/SR composites were prepared with the outer two insulating layers of SR while middle three dielectric layers of MWCNT@PNs filled SR. The multilayered structure further hindered the formation of conductive pathways through the composites, promising a high breakdown strength of the composites. Therefore, the multilayered MWCNT@PNs/SR composites exhibited increased ε, maintained low Young's modulus and electrical breakdown strength compared with pure SR of the same five-layered structure. Among them, the composite with uniformly distributed MWCNT@PNs (m-1: 1: 1) showed a highest actuation strain of 11.9% (at 19.6 kV mm−1), which was 4.1 times higher than that of SR (2.9% at 19.1 kV mm−1).