Fecha de publicación: 13/11/2024 Fuente: Polymers Polymers, Vol. 16, Pages 3162: Amino-Functionalized Metal–Organic Framework-Mediated Cellulose Aerogels for Efficient Cr(VI) Reduction
Polymers doi: 10.3390/polym16223162
Authors:
Fan Yang
Dandan Hao
Miaomiao Wu
Bo Fu
Xiongfei Zhang

Industrialization activities have increased the discharge of wastewater that is polluted with hexavalent chromium (Cr(VI)), posing risks to ecosystems and humans. The photocatalytic reduction of Cr(VI) is viewed as a promising method for the removal of Cr(VI) species. However, developing photocatalysts with the desired catalytic activity, recyclability, and reusability remains a challenge. Herein, a composite aerogel was designed and fabricated with a Ti-based metal–organic framework (MIL-125-NH2) and carboxylated nanocellulose. MIL-125-NH2 presents a strong visible-light response, and the interactions between the amino groups of MIL-125-NH2 and the carboxyl groups of cellulose produce a strong interface affinity in the composites. The as-prepared aerogels exhibited a micro/macroporous structure. At an optimal MIL-125-NH2 loading of 55 wt%, the MC-5 sample showed a specific surface area of 582 m2·g−1. MC-5 achieved a photocatalytic Cr(VI) removal efficiency of 99.8%. Meanwhile, the aerogel-type photocatalysts demonstrated good stability and recycling ability, as MC-5 maintained a removal rate of 82% after 10 cycles. This work sheds light on the preparation of novel photocatalysts with three-dimensional structures for environmental remediation.